Thermodynamics of Ion-Containing Polymer Blends and Block Copolymers
نویسندگان
چکیده
منابع مشابه
Thermodynamics of ion-containing polymer blends and block copolymers.
We develop a theory for the thermodynamics of ion-containing polymer blends and diblock copolymers, taking polyethylene oxide (PEO), polystyrene and lithium salts as an example. We account for the tight binding of Li^{+} ions to the PEO, the preferential solvation energy of anions in the PEO domain, the translational entropy of anions, and the ion-pair equilibrium between EO-complexed Li^{+} an...
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ژورنال
عنوان ژورنال: Physical Review Letters
سال: 2011
ISSN: 0031-9007,1079-7114
DOI: 10.1103/physrevlett.107.198301